ESPN has a silly "ranking all playoff teams" article. It is what it is, but I found their top 3 interesting. Each was great and had a crazy-impressive pair of wins in the playoff.
So while worrying about 36 teams is a bit much, I figure we could pick a "best" from those 3 (or some other team, if you feel passionate about them). I'll try to check in and specify what your "other" team was ranked in the article.
The teams/resumes:
2020 Alabama - a unique case, due to covid...played 10 conference foes, a CCG, then 2 playoff teams...no OOC cupcakes. Won them all by an average score of 49-19. Went 13-0 with playoff wins over ND (31-14) and OSU (52-24).
They had 3 players in the top 5 of Heisman voting (QB Jones, RB Harris), including the winner (WR Smith). Only 1 win was by fewer than 14 points. Scored 50+ points 7 times. And their kicker didn't miss a FG.
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2019 LSU - the offense is legendary....15-0 record, avg score of 48-22. Defense wasn't great for a NC winner, but it didn't matter. Averaged 402 yds passing per game. Heisman winner QB Burrow threw 60 TD passes with only 6 INTs. Oh, also had a 1,400 yard rusher (Edwards Helaire).
Beat five top-10 teams BEFORE the playoff. Scored 105 pts in their two playoff games vs OU (63-28) and Clemson (42-25). Did have 3 close wins, though.
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2018 Clemson - 15-0 record, beat the hell out of both playoff opp: 30-3 vs ND, 44-16 vs Bama. QB was #1 overall draft pick (Lawrence) AND they ran for 250 yds per game @ 6.6 ypc (Etienne & Co.).
Held 9 opp to ten points or less. Had one of the best defensive lines ever. Weak regular season schedule made people wary, but dominated #3 ND and #1 Bama in playoff. Two close games early.